|
Concentrated nitric acid is required for
many chemical processes. It is produced by feeding the aqueous
nitric acid resulting from the oxidation of ammonia (composition
about 65% HNO3 by mass), into a concentration unit along with
60 - 67% by mass of concentrated sulphuric acid, H2SO4. This has
two functions:
- The concentrated sulphuric acid is
a dehydrating agent and will remove water from the nitric acid
- The concentrated sulphuric acid removes
the azeotrope (the constant boiling mixture at 68.5% HNO3) from
the nitric acid/ water system. Distillation of this mixture
produces a vapour with 99% HNO3 (plus some nitrogen dioxide
and oxygen from the dissociation of nitric acid during distillation
|